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Thermodynamics

Isentropic Ideal-Gas Pressure–Volume Relation

Reversible adiabatic compression or expansion of a fixed mass of calorically perfect ideal gas keeps PV raised to the heat-capacity ratio constant.

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Source & review

Difficulty

Intermediate

Read time

4 min

Prerequisites

Consistent SI units, algebra, and the physical assumptions listed below

Review statusNeeds review

Source

Teng-Jui Lin — Equation Sheets

Adapted from Teng-Jui Lin, Equation Sheets — Mechanical Engineering, under CC BY 4.0.

Adapted notation and added original explanations, variables, assumptions, applications, and a worked example. Made the ideal-gas, constant-γ, reversible-adiabatic assumptions explicit.

Definition
Understanding the core concept

Reversible adiabatic compression or expansion of a fixed mass of calorically perfect ideal gas keeps PV raised to the heat-capacity ratio constant. The relation predicts the pressure change from a volume ratio without assuming the temperature stays constant.

Variables & Units
Understanding each component
SymbolMeaningUnits
Initial absolute pressure
Final absolute pressure
Initial gas volume
Final gas volume
Constant heat capacity ratio
Real-World Applications
Where this formula is used in practice

Piston compression

Estimate a pressure rise for a reversible adiabatic volume change.

Gas-cycle models

Connect two idealized compression or expansion states.

Worked Example
Step-by-step calculation with real numbers

Problem

A gas at 100000 Pa is compressed reversibly and adiabatically from 0.010 to 0.005 m³. Use constant γ = 1.4.

Given

Solution

1
2

Final Answer

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