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Thermodynamics

Polytropic Boundary Work

A quasi-equilibrium polytropic path follows PVⁿ = constant.

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Source & review

Difficulty

Intermediate

Read time

4 min

Prerequisites

Consistent SI units, algebra, and the physical assumptions listed below

Review statusNeeds review

Source

Teng-Jui Lin — Equation Sheets

Adapted from Teng-Jui Lin, Equation Sheets — Mechanical Engineering, under CC BY 4.0.

Adapted notation and added original explanations, variables, assumptions, applications, and a worked example. Integrated the source's general polytropic relation with work-by-positive convention. Did not reuse its incorrect isothermal work expression in the adiabatic section.

Definition
Understanding the core concept

A quasi-equilibrium polytropic path follows PVⁿ = constant. Integrating pressure with respect to volume gives the boundary work done by the gas, with positive work for expansion under the convention used here.

Variables & Units
Understanding each component
SymbolMeaningUnits
Boundary work done by the system
Initial absolute pressure
Final absolute pressure
Initial volume
Final volume
Polytropic exponent
Real-World Applications
Where this formula is used in practice

Piston–cylinder analysis

Evaluate boundary work for a specified polytropic path.

Process comparison

Compare compression work under different exponents and conventions.

Worked Example
Step-by-step calculation with real numbers

Problem

A gas expands from P₁ = 200000 Pa and V₁ = 0.10 m³ to V₂ = 0.20 m³ along PV^1.3 = constant. P₂ = 81225.24 Pa follows from that path.

Given

Solution

1
2

Final Answer

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