Connect a reaction’s standard Gibbs energy change with its equilibrium constant.
Difficulty
Intermediate
Read time
3 min
Prerequisites
Algebra, logarithms, and molar quantities
Source
OpenStax, Chemistry 2e, §16.4Adapted from Teng-Jui Lin’s CHEM 145 equation sheet. The linked textbook reference was used to check the equation and its physical context. Pending editorial review.
Adapted from Teng-Jui Lin, Equation Sheets, under CC BY 4.0.
FormuLab adapted notation and chemical symbols, added variable meanings, units, applicability conditions, and an original worked example.
The standard reaction Gibbs energy determines the equilibrium constant at the stated temperature. A dimensionless K greater than one corresponds to a negative standard Gibbs energy change for the reaction as written.
| Symbol | Meaning | Units |
|---|---|---|
| Standard reaction Gibbs energy change | ||
| Molar gas constant | ||
| Absolute temperature | ||
| Dimensionless thermodynamic equilibrium constant |
Relate standard reaction energy to an equilibrium constant.
Convert a measured equilibrium constant into standard Gibbs energy.
At 298.15 K a reaction has dimensionless equilibrium constant K = 10.0. Find its standard reaction Gibbs energy change.
Adapted from Teng-Jui Lin’s CHEM 145 equation sheet. The linked textbook reference was used to check the equation and its physical context. Pending editorial review.
Adapted from Teng-Jui Lin, Equation Sheets, under CC BY 4.0.
FormuLab adapted notation and chemical symbols, added variable meanings, units, applicability conditions, and an original worked example.
Assumptions
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